Steve: He didn't really need an introduction to Bucky; they were like brothers during the 40s.
Tony: You were an only child, and your mom had died during childbirth. So when he met Phil, it was a bit tense for him. They actually got close, and that's why it hit Tony so hard when Coulson died.
Bruce: Tony didn't really need an introduction; he's freaking Iron Man...
Thor: Wanda had tricked his mind, and Pietro died. But when they briefly and officially met, the twins liked their baby sister's boyfriend.
Loki: Wasn't much of an introduction; Bruce wasn't really fond of Loki, but got along with him for you.
Clint: You and Natasha both met Clint when he was assigned to kill the both of you. Needless to say...no introduction needed.
T'Challa: Clint met T'Challa around the same time everyone else did. He liked the Wakandan Prince (at the time he was prince) and thought he was a good match for you.
Bucky: Steve knew Bucky, and Bucky knew Steve. They were best friends before Steve went all Captain America.
Pietro: He met Thor before, but he was terrified of meeting your brother, Loki. Loki was a little scary at first, but then he eased up once he got to know the Sokovian quickster.
Peter: Your dad was Nick Fury. The Nick Fury. The spy of all spies. Peter was pale white after meeting him, and that was normal. Who wouldn't be intimidated by the director of SHIELD?
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Avengers Preferences {UNDER HEAVY EDITING}
RomancePreferences for the following characters from Marvel's MCU: Steve Rogers Tony Stark Bruce Banner Thor Odinson Loki Laufeyson Clint Barton Bucky Barnes Pietro Maximoff Peter Parker Vision Natasha Romanoff Wanda Maximoff I won't be adding characte...