The order of the characters will go as follows... 1. Anthony "Tony" Stark/Iron Man 2. Steven "Steve" Rodgers/Captain America 3. Thor Odinson 4. Natasha Romanoff/Black Widow 5. T'Challa/Black Panther 6. Peter Parker/Spider-Man 7. Wade Wilson/Deadpool 8. James "Logan" Howlett/Wolverine 9. Edwin "Eddie" Brock Jr./ Venom As for the actors portraying them, think of them like their movie counterparts...well for Spidey and Venom their more recent movie counterparts.