Tiberius Salvatore: The eldest brother
57 parts Complete In desperate need of editing, which I haven't started yet.
Book 1
Rio Salvatore. The eldest Salvatore brother, turned at 25 years of age. He, unlike his brothers, never fell for Katherine's mind games. She resented him for this very reason, and made it her life's mission to make his life as horrible as could be. Turning him into a vampire, she made his life a living hell. Now back in Mystic falls to find out his brothers were actually alive, he starts to hate Elena too. She was more like Katherine than she thought.
Starts in season two but stuff from season 6 will crop up. So there will be spoilers