After the CIA loses Napoleon Solo to U.N.C.L.E, Ann Marie becomes the top agent. Needless to say she catches the eye of Waverley, due to the fact she is willing to do anything to close a case. After she gives her reluctant approval, she joins U.N.C.L.E, leaving everything she's worked for behind. Now having to deal with two alpha males and Gaby, they set out to save the world