High school hadn't been a walk in the park for Peter. One would argue that high school was tough for most people, but he thought he had had it worse, and he wasn't wrong. Most people didn't lead a secret double life they had to hide from the world lest it jeopardize their other, normal life. So, if someone had asked Peter back then what he wanted to do with his life, he wouldn't have known what to answer; or rather, he knew what he wanted to say but feared the answer would disappoint.
Peter Parker wanted to apply for College and get a degree in physics, but that hope was shot dead when he received his report card on his last year. Being the friendly neighborhood Spider-Man did not allow for much study time, and his grades suffered from that. The consequence of this was that Ned got the scholarship for the University he wanted, and Peter didn't.
He had thought that was it – he couldn't ask his Aunt May to take up a loan to pay for his tuition, and what was he going to do with that degree anyway? Being a superhero didn't require going to college. That was when Pepper Potts knocked on his door – metaphorically – and pulled a joker out of her sleeve.
Tony, ever ahead of everyone else, even in death, had opened an secret account in Peter's name that he would only access at age eighteen, and that contained a frankly obscene amount of money meant to be his college fund (but that would surely last him a lifetime and leave him wanting for nothing). At least, he wouldn't have to live in a shared dorm room and that had to count for something, especially when you considered he would have had to wash his Spidey-suit in the laundromat.
This unexpected divine intervention from late Tony Stark had sparked hope in Peter's heart and he dared wish for things once again. He ended up going to a different college than Ned, but he didn't let that dampen his mood: he had to consider this a fresh start. And a fresh start it was because he knew no one, he was far from his best friend, his aunt and even more so from MJ who had left him earlier during their senior year on the ground that high school crushes don't last.
He had been miserable at first, but quickly understood where she was coming from. They stayed good friends, though they tried to keep their interactions to a minimum and never hung out alone again after their breakup.
Despite all of this, Peter Parker felt ecstatic, like there was electricity in the air, when he walked on his new campus – at UC, Davis - , feeling like any other anonymous student in the crowd. He wouldn't waste his chance at starting fresh, he owed it to himself. It was hell week, the worst time for freshmen; Peter thought he was the only person looking forward to being hazed.
When he moved out of his and Aunt May's apartment in Queens, he pictured a lot of things for his new life. Going to college, becoming an adult, being independent and surveying a new territory. He hoped to make friends quickly, have interesting classes, good grades, maybe get a girlfriend at some point - that was the dream. He never expected to find one on the first day, especially not during a three-legged race because the resident jock asked him to switch partners so he could be with the local cheerleader type girl.
"Hey man," the tall blond had greeted him, slapping his shoulder so hard Peter thought he might have dislocated it if he wasn't super-strong. "I got an idea. What about you go over there and ask the hot red head if she wants to trade places with you?"
This felt oddly familiar to Peter, being the loser people tried to get rid of. He looked over at the above-mentioned red head and agreed that she was very pretty. She was standing next to a shorter brunette and they were laughing together. He always admired the way girls flocked together and could act as if they had known each other all their lives even though they just met.

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Peter Parker Oneshots
FanficIn progress collection of Peter Parker oneshots. Hurt/Comfort. Aged Up!Peter balancing out personal and superhero life. College AUs. Does not take into account the Far From Home post-credit scenes; spoiler-free.