Her headphones don't have anything playing on them. She wears them for two reasons:
1) So people don't talk to her. She hates getting distracted, not to mention she's as socially awkward as her male counterpart.
2) Because they block out sound. For all her shouting, she hates loud noises.
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Hetalia Headcanons
FanfictionI have a lot of these. Some of them affect my stories. It makes sense to write them down.