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Natasha, Bruce and surprisingly, Thor, are the only Avengers that have heard Tony play the piano seriously.

It wasn't Natasha or Bruce that heard Tony play the piano first. After Tony found Thor awake in the common room one night and Thor told him about his mother's death, he offered to play him somthing to maybe help him go to sleep; shyly explainning that his mother used to do that for him whenever he couldn't sleep or relax.

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