Warning to non-multishippers: different ships you may not agree with are mentioned. Some are not canon characters.
Tomura
Your step parent is Dabi. Wow, so cool! Your messed up parenting just got worse! You're already a rude kid, but with Dabi around you're bound to pick up even worse traits. Not like they'll mind. You still find most of your time with your Daddy but Dabi (who you eventually come to call Papa) takes up Shigaraki's time when you're not involved and when he is planning what ever great scheme he has, you Dabi play target practice with some unsuspecting people that wander a little too close to the hideout.Dabi
Ah, this one he had to have you stay silent about when around the League. Your step parent is Hawks. You like Hawks as a step parent because it gives you a balance. You can see the way villains see the world and how heroes see it too. While Kurogiri still babysits you, it's a lot less. They know Dabi is married just don't know to who and honestly the League doesn't care. Most of them think it's a poor sap he forced to marry him. When Dabi has League work and but Hawks doesn't have Hero work, you two hang out. Most of your time with your step dad who you just bird dad is spent being carried by him during a casual flight. Also, ice cream. Lots of ice cream. A lot of Dabi and Hawks's time together is either with you or when you're asleep. (Wink ;D)Kurogiri
After the disaster with your mother, he didn't think he'd find interest in anyone again. Then he met her. Your step mother isn't actually a canon character, but an OC of mine. Your step mother is a calm young lady who originally was a normal civilian who earned her cash by babysitting, pet-sitting, and house-sitting. She has a quirk called Angel Lure that makes her voice soft and angelic as she sings. Don't be misguided and think she came to your father's side willingly. Not all villains are like lucky like Dabi. She was kidnapped and she found no hope but to submit to your father. You being the naïve and innocent youngling you were at the time made it easier. No one knows just how much time those two have to themselves in the bar and you spend your time with them almost as much...until 8:00 comes around.Stain
You don't have a step parent. Stain is single since his work calls for that and he's already devoted most of his free time to you.Twice
Somehow TOGA of all people is your step mother. What started out as her babysitting you turned into flirting and one day... the ring. They don't separately do anything now and they love spoiling you.Toga
Toga isn't married but you have a potential step parent, a little someone called Izuku Midoriya. It was an odd matching and extremely hard for them to hide. Izuku does play a daddy role for you that you desperately need.Spinner
Spinner is not with anyone officially but he does stalk this pretty woman going to U.A in the Support department. Your father has indeed gushed about her to you, even if you don't understand.
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BNHA Villains: Parent Scenarios
FanfictionPeople I plan to write, may add more: Tomura Dabi Kurogiri Stain Twice Toga Spinner Overhaul