Infinity War: Ascent to Space

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After finishing his battle, Iron Man managed to locate the Q-Ship and flew towards the sky while deploying Item 17A from the New Avengers Facility. Beginning to run out of oxygen, Spider-Man removed his mask as he unable to breathe as much as he can. Iron Man commanded Spider-Man to let go and fall in order to catch him. Spider-Man told Iron Man that he must save the wizard as he was told by him, but Iron Man retorted his statement that he won't be able to breathe as the ship moved upward.

As he exhaustively starts to pass out, Spider-Man was nearly suffocated as the ship left Earth's atmosphere and fell off the ship as he couldn't breathe anymore. Falling down, Spider-Man was rescued by the intervention of Iron Man, who summoned the Iron Spider Armor. As the suit manifested around him with nanotech particles, Spider-Man swiftly recovered with an acrobatic landing and was able to breathe and contact Iron Man.

As he catches up with Parker, Stark told him farewell up on the ship and commanded F.R.I.D.A.Y. to send him back to Earth, using his parachute to descend into orbit. Stark latched onto the hull to cut a hole and board the Q-Ship, to look for wherever Doctor Strange and Ebony Maw went. Getting a call from Pepper Potts, Stark answered the call and told her that he was on the ship, only to lose reception halfway at Potts' expense.

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