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After being attacked by Lucius and nearly killed by Sister Lily, Asta and Liebe were sent to an unknown land with nothing but a desert and a neverending night. They were found unconscious by a group of people in white clothing and brought them somewhere. After sometime, they wake up to find that they were all healed and in unfamiliar bedrooms. Shortly after waking up, they were greeted a pair of young girls who looked about their age. They were later brought to the ruler of the land and they learned that they were a world called Hueco Mundo, and after learning of their predicament, the ruler of Hueco Mundo offered to give and train them to use the powers of what are called Arrancars. The devil and magic knight accepted the offered and began their training. How powerful will the brothers become?